List of ions

This is a list of ions, indexed according to the periodic table.

Alkali metals and alkaline earth metals

Elements

Ions

Colors

Examples

Properties

H

H+

colorless

HClO4

H

colorless

NaH

H + H2O = OH + H2(g)

Li

Li

Li+(calix[4]pyrrole)Li

Li+

colorless

LiNO3

(abbr. for [Li(H2O)4]+ or [Li(H2O)6]+)
Flame test of Li+ is crimson red

Na

Na+

colorless

NaCl

(abbr. for [Na(H2O)n]+, n=4 - 6)
Flame test of Na+ is yellow

K

K+

colorless

KI

(abbr. for [K(H2O)n]+, n=6, 7, 8)
Flame test of K+ is lilac

Rb

Rb+

colorless

RbCl

Cs

Cs+

colorless

CsCl

Be

Be2+

colorless

BeSO4

very toxic

BeF42-

colorless

(NH4)2BeF4

BeCl42-

colorless

Cs2BeCl4

unstable

[Be(OH)4]2−

colorless

Na2[Be(OH)4]

[Be(OH)4]2- + 4 H+ = Be(OH)2(s) + 2 H2O

Mg

Mg2+

colorless

MgCl2

Ca

Ca2+

colorless

CaCl2

Sr

Sr2+

colorless

SrCl2

Ba

Ba2+

colorless

BaCl2

toxic
Ba2+ + CO32- = BaCO3
Ba2+ + SO42- = BaSO4

Group 3 elements

Elements

Ions

Colors

Examples

Properties

Sc

Sc3+

colorless

Sc(NO3)3

[Sc(OH)6]3-

colorless

K3[Sc(OH)6]

Y

Y3+

colorless

La

La3+

colorless

Ce

Ce3+

colorless

Ce(NO3)3

Ce4+

orange-yellow

Ce(SO4)2

Pr

Pr3+

green

Pr(NO3)3

Th

Th4+

colorless

Th(NO3)4

Th4+ + 4 OH = Th(OH)4(s)

U

U3+

brown-red

UCl3

U4+

green

UO2+

unstable

UO22+

yellow

UO2(NO3)2

Group 4 - 7 elements

Elements

Ions

Colors

Examples

Properties

Ti

Ti3+

violet

Ti2(SO4)3

(abbr. for [Ti(H2O)6]3+)
reductant

TiO2+

(abbr. for [TiO(H2O)5]2+)

TiF62-

colorless

K2TiF6

TiCl62-

yellow

Cs2TiCl6

TiBr62-

red

Zr

Zr4+

colorless

Zr(NO3)4.5H2O

(abbr. for [Zr(H2O)8]4+)

ZrO2+

colorless

ZrO(NO3)2

(abbr. for [Zr4(OH)8(H2O)16]8+)

Hf

Hf4+

colorless

(abbr. for [Hf(H2O)8]4+)

Cr

Cr2+

light blue

CrSO4

(abbr. for [Cr(H2O)6]2+)
reductant

Cr3+

grayish green

Cr(NO3)3

(abbr. for [Cr(H2O)6]3+)

CrO42-

orange

K2CrO4

Cr2O72-

yellow

K2Cr2O7

Group 8 - 10 elements

Elements

Ions

Colors

Examples

Properties

Fe

[Fe(CO)4]2-

Fe2+

light green

FeSO4.7H2O

Fe2+ + 2 OH = Fe(OH)2
Fe2+ + CO32− = FeCO3

Fe3+

pale purple

NH4Fe(SO4)2

[Fe(phen)3]2+

dark red

[Fe(phen)3]3+

light blue

FeO42-

purple

K2FeO4

strong oxidant

Co

[Co(CO)4]

K[Co(CO)4]

oxidized in air

Co2+

pink

Co(NO3)2.6H2O

[Co(NH3)6]2+

[Co(NH3)6]3+

orange

[Co(NH3)6](NO3)3

stable

Ni

Ni2+

green

Ni(NO3)2

Ni2+ + 2 OH = Ni(OH)2

[Ni(NH3)6]2+

blue

[[tetrafluoronickelate|[NiF4]2-]]

[[tetrachloronickelate|[NiCl4]2-]]

[[tetrabromonickelate|[NiBr4]2-]]

[Ph4P]2[NiBr4]

[[tetraiodonickelate|[NiI4]2-]]

red

[[cyanonickelate|[Ni(CN)4]2-]]

yellow

K2[Ni(CN)4]

Group 11 - 12 elements

Elements

Ions

Colors

Examples

Properties

Cu

Cu2+

blue

Cu(NO3)2

(abbr. for [Cu(H2O)4]2+ or [Cu(H2O)6]2+

[Cu(NH3)4]2+

dark blue

[Cu(NH3)4](NO3)2

decompose by acids

Ag

Ag+

colorless

AgNO3

2 Ag+ + 2 OH = Ag2O + H2O (r.t.)

[Ag(NH3)2]+

colorless

[Ag(NH3)2]OH

decompose by acids

AgCl2

colorless

AgCl in conc. Cl solution

[Ag(CN)2]

colorless

toxic

Au

AuCl4

yellow

NaAuCl4

AuBr4

purple

KAuBr4

Zn

Zn2+

colorless

Zn(NO3)2

white in silicate garden

[Zn(NH3)4]2+

colorless

[Zn(NH3)4](OH)2

[Zn(OH)4]2-

colorless

[Zn(CN)4]2-

colorless

K2[Zn(CN)4]

toxic

Cd

Cd2+

colorless

Cd(NO3)2

Hg

Hg22+

colorless

Hg2(NO3)2

(abbr. for [Hg2(H2O)6]2+)

Hg2+

colorless

Hg(NO3)2

(abbr. for [Hg(H2O)6]2+
very toxic

Boron group and carbon group

Elements

Ions

Colors

Examples

Properties

B

BH4

colorless

NaBH4

strong reductant

BF4

colorless

HBF4

non-coordinating anion

Al

Al3+

colorless

Al(NO3)3

C

CO32-

colorless

Na2CO3

HCO3

colorless

NaHCO3

CN

colorless

KCN

very toxic
CN + H+ = HCN

Si

SiO32-

colorless

Na2SiO3

SiO32− + 2 H+ = H2SiO3

SiF62-

colorless

Na2[SiF6]

Ge

GeO32-

colorless

Na2GeO3

Sn

Sn2+

colorless

SnCl2

Reductant
exist in acidic solution

Pb

Pb2+

colorless

Pb(NO3)2

Pb2+ + 2 I = PbI2(s)

Pnictogens and chalcogens

Elements

Ions

Colors

Examples

Properties

N

NH4+

colorless

NH4Cl

N3-

Na3N

react with water

NH2

NaNH2

react with water

N3

NaN3

very toxic

NO2

NaNO2

toxic

NO3

colorless

KNO3

oxidant

P

PH4+

colorless

PH4I

dec. in water

PO43-

colorless

Na3PO4

P2O74-

colorless

Na4P2O7

PF6

colorless

KPF6

non-coordinating anion

O

OH

colorless

NaOH

corrosive

O22−

Na2O2

ionic peroxides react with water

S

S2−

colorless

Na2S

S22-

Na2S2

S22- + 2 H+ = H2S + S

S2O32-

colorless

Na2S2O3

S2O32- + 2H+ = SO2 + S + H2O

SO32-

colorless

Na2SO3

SO32- + 2 H+ = H2O + SO2

SO42-

colorless

K2SO4

Halogens and noble gases

Elements

Ions

Colors

Examples

Properties

F

F

colorless

CsF

HF2

colorless

KHF2

unstable towards heat

Cl

Cl

colorless

NaCl

Cl + Ag+ = AgCl

OCl

NaOCl

strong oxidant

ClO2

NaClO2

ClO3

colorless

KClO3

ClO4

colorless

KClO4

Br

Br

colorless

KBr

BrO3

colorless

KBrO3

oxidant

I

I2+

blue

I3+

red-brown

I

colorless

KI

reductant
2 I + Cl2 = 2 Cl + I2
2 I + Br2 = 2 Br + I2

I3

CsI3

IO3

colorless

KIO3

ICl4

KICl4

IO4

colorless

KIO4

He

HHe+

extremely strong acid

Ar

HAr+

found in space

Xe

XeO64-

Na4XeO6

strong oxidant

HXeO4

CsHXeO4